Teardowns of electronics in 2019.
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  112. <TD HEIGHT="19">November 17, 2017</TD>
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  119. <H1>NiCad Battery Charging Basics</H1></TD>
  120. <TD></TD>
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  122. <A HREF="NiCad-NiMH-Catalog.htm"><IMG SRC="z/5730ss.jpg" BORDER="0"
  123. ALT="Wall mount chargers 3 cell to 12 cell versions" WIDTH="118"
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  125. catalog page</A> </TD>
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  133. <H2 ALIGN="Left">NiCad (NiCd, Nickel Cadmium) Battery Charging</H2>
  134. <H2 ALIGN="Left">Nickel Battery Charging Basics</H2>
  135. <P ALIGN="Left">NiCad and NiMH batteries are amongst the hardest
  136. batteries to charge. Whereas with lithium ion and lead acid batteries you can
  137. control overcharge by just setting a maximum charge voltage, the nickel based
  138. batteries don't have a "float charge" voltage. So the charging is based on
  139. forcing current through the battery. The voltage to do this is not fixed in
  140. stone like it is for the other batteries. </P>
  141. <P ALIGN="Left">This makes these cells and batteries especially
  142. difficult to charge in parallel. This is because you can't be sure that each
  143. cell or pack is the same impedance (or resistance), and so some will take more
  144. current than others <I>even when they are full.</I> This means that you need to
  145. use a separate charging circuit for each string in a parallel pack, or balance
  146. the current in some other way, for example by using resistors of such a
  147. resistance that it will dominate the current control. </P>
  148. <P ALIGN="Left"><FONT COLOR="#000000">The coulometric charging
  149. efficiency of nickel cadmium is about 83% for a fast (C/1 to C/0.24) charge,
  150. and 63% for a C/5 charge. This means that at C/1 you must put in 120 amp hours
  151. in for every 100 amp hours you get out. The slower you charge the worse this
  152. gets. At C/10 it is 55%, at C/20 it can get less than 50%. (These numbers are
  153. just to give you an idea, battery manufacturers differ).</FONT></P>
  154. <P ALIGN="Left"><FONT COLOR="#000000">When the charge is complete
  155. oxygen starts being generated at the nickel electrode. This oxygen diffuses
  156. through the separator and reacts with the cadmium electrode to form cadmium
  157. hydroxide. This causes a lowering of the cell voltage which can be used to
  158. detect the end of charge. This so-called minus delta V/ delta t bump that is
  159. indicative of end-of-charge is much less pronounced in NiMH than NiCad, and it
  160. is very temperature dependent. Many of the chargers listed here use a
  161. sophisticated algorithm that uses the -deltaV to accurately charge NiMH and
  162. NiCad packs <A
  163. HREF="NiCad-NiMH-Catalog.htm">/NiCad-NiMH-Catalog.htm</A></FONT></P>
  164. <P ALIGN="Left"><FONT COLOR="#000000">As the battery reaches
  165. end-of-charge oxygen starts to form at the electrodes, and be recombined at the
  166. catalyst. This new chemical reaction creates heat, which can be easily measured
  167. with a thermistor.. This is the safest way to detect end-of-charge during a
  168. fast charge. This method is often used with multi-cell packs and the 20, 30,
  169. and 40 cell pack chargers here use a thermistor
  170. <A HREF="NiCad-NiMH-Catalog.htm">/NiCad-NiMH-Catalog.htm</A></FONT></P>
  171. <P ALIGN="Left"><FONT COLOR="#000000">Nickel cadmium battery
  172. chargers should cut the charge off when the temperature exceeds the maximum
  173. charging temperature, typically 45 degrees C for a controlled fast charge, and
  174. 50 degrees C for an overnight or fast charge.</FONT></P>
  175. <H2 ALIGN="Left">Overnight Battery Charging</H2>
  176. <P ALIGN="Left">The cheapest way to charge a nickel cadmium battery
  177. is to charge at C/10 (10% of the rated capacity per hour) for 16 hours.. So a
  178. 100 mAH battery would be charged at 10 mA for 16 hours. This method does not
  179. require an end-of-charge sensor and ensures a full charge. Cells can be charged
  180. at this rate no matter what the initial state of charge is. The minimum voltage
  181. you need to get a full charge varies with temperature--at least 1.41 volts per
  182. cell at 20 degrees C. The best charging practice is to use a timer to prevent
  183. overcharging to continue past 16 hours. An example of this kind of charger is
  184. shown at <A HREF="Ni-6-200.htm">/Ni-6-200.htm</A> . This charger uses a
  185. microprocessor to report the state of charge via an LED as well as performing
  186. the timing function. </P>
  187. <H2 ALIGN="Left">Faster Charging</H2>
  188. <P ALIGN="Left"><FONT COLOR="#000000">Some nickel cadmium cells are
  189. designed to be "quick chargeable." This is just a timed charge at C/3 for 5
  190. hours, or C/5 for 8 hours. This is risky because the battery should be fully
  191. discharged before charging. If the battery still has 90% of its capacity when
  192. the timer starts you would have a good chance of venting the battery. One way
  193. to ensure this doesn't happen is to have the charger automatically discharge
  194. the battery to 1 volt per cell, then turn the charger on for 5 hours. The
  195. advantage of this method is to eliminate any chance of battery memory.
  196. PowerStream does not currently have such a charger, but the microprocessor
  197. board used in the C/10 charger <A
  198. HREF="NiMH-NiCad-solar-charge-controller.htm">/NiMH-NiCad-solar-charge-controller.htm</A>
  199. could easily be modified to do the discharge. A power dissipating package would
  200. be needed in order to dissipate the energy from a partially charged battery in
  201. a reasonable amount of time. </FONT></P>
  202. <H2 ALIGN="Left">Fastest Charging</H2>
  203. <P ALIGN="Left"><FONT COLOR="#000000">If a temperature or voltage
  204. monitor is used NiCad batteries can be charged at rates up to 1C (in other
  205. words 100% of the battery capacity in amp-hours for 1.5 hours). The PowerStream
  206. battery charge controller shown in <A HREF="Product3.htm">/product3.htm</A>
  207. does this, as does the battery management board shown in <A
  208. HREF="Product5.htm">/product5.htm.</A> </FONT></P>The termination can be done
  209. with minus delta V, when the battery voltages drops -10 to -20 mV per cell. To
  210. terminate the charge on temperature requires a temperature slope
  211. measurement.<BR><BR>This board also has the ability to sense voltage and
  212. current for more sophisticated algorithms required for ultra-fast charging.
  213. These algorithms require constant monitoring of the voltage, temperature, and
  214. sometimes pressure, to actively determine the amount of current a battery can
  215. take without damage. This is sometimes called a smart charge, or a controlled
  216. fast charge.<BR><BR>A cheaper version of the fast charger can be made by just
  217. monitoring absolute temperature. The charge rate is set at C/2 until 45 degrees
  218. C is reached, then switched over to a C/10 charge to complete the charge. This
  219. is the most common NiCd fast charger of the 1960's through the 1980s because it
  220. could be controlled by a simple bi-metallic thermostat switch mounted on the
  221. battery.<BR><BR>
  222. <H2>Trickle Charging Nickel Batteries</H2><BR>In a standby mode you
  223. might want to keep a nickel cadmium battery topped up without damaging the
  224. battery. This can be done safely at a current of between 0.05 C and .06 C. The
  225. voltage required for this is dependent on temperature, so be sure to regulate
  226. the current in the charger.<BR>
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  271. <P ALIGN="CENTER"><FONT SIZE="-2">&copy; Copyright 2000, 2002, 2003, 2004, 2005, 2006, 2008,2009, 2010, 2011, 2012, 2013, 2014, 2015, 2016, 2017, 2018 <br> Lund Instrument Engineering, Inc. All rights reserved. by Mark W. Lund </FONT><br><a href="https://plus.google.com/109788128074027893638?rel=author">Google Author Verification</a> </P> </TD><SCRIPT SRC="/__utm.js"><SCRIPT SRC="http://www.google-analytics.com/urchin.js" TYPE="text/javascript">
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